Tetrachlorophenyl metal-porphyrin compound and its preparation and application


Application Number: 00109300
Application Date: 2000.06.15
Publication Number: 1277199
Publication Date: 2000.12.20
Priority Information:
International: B01J31/12;C07D487/22
Applicant(s) Name: Beijing Polytechnic Univ.
Address:
Inventor(s) Name: She Yuanbin;Chen Yuyun;Zhong Rugang
Patent Agency Code: 11203
Patent Agent: zhang hui
Abstract Tetrachlorophenyl metal-porphyrin compounds have a general formula of C44H24N4Cl4M5, where M is metal Cu, Co, Zn or Fe. During its preparation, chlorobenzaldehyde, inorganic salt of the metal and pyridine are reacted in a high-pressure reactor at 175 deg.C for 48 hr; and the product is separated in silica column to obtain required product. The compounds are used as catalyst in the synthesis of nitro benzoic acid to raise the yield. In addition, it is used as simulated biological enzyme catalyst for catalyzing the oxidation of various hydrocarbons, and may be used in the fields of semiconductor, superconductor, specially polymer and as anticarcinogen intermediate, etc.